876372-94-0

Basic information

• Product Name: Disulfide, bis(2,4-difluorophenyl)
• CAS NO: 876372-94-0
• Molecular Formula: C12H6F4S2
• Molecular Weight: 290.305
• Mol File: 876372-94-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Disulfide, bis(2,4-difluorophenyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Disulfide, bis(2,4-difluorophenyl)(876372-94-0)
• EPA Substance Registry System: Disulfide, bis(2,4-difluorophenyl)(876372-94-0)

Safety Data

• Hazardous Substances Data: 876372-94-0(Hazardous Substances Data)

Upstream product

• 348-57-2 2,4-difluorobromobenzene 
• 1996-44-7 2,4-difluorothiophenol 

Downstream Products

• 1522408-96-3 (2,4-difluorophenyl)pentafluoro-λ⁶-sulfane 
• 1522408-87-2 2,4-difluorophenylsulfur chlorotetrafluoride 
• 876372-77-9 methyl 3-{6-[(2,4-difIuorophenyl)thio][1,2,4]triazolo[4,3-a]pyridin-3-yl}benzoate 
• 876461-39-1 C₁₆H₁₃F₂N₃S 
• 876372-60-0 3-tert-butyl-6-[(2,4-difluorophenyl)thio][1,2,4]triazolo[4,3-a]pyridine 
• 876372-50-8 6-[(2,4-difluorophenyl)thio]-3-isopropyl-5-methyl[1,2,4]triazolo[4,3-a]pyridine 

Relevant articles and documents

Metal Organic Framework 199- Catalyzed Domino Sulfur-Coupling and Transfer Reactions: The Direct Synthesis of Symmetric Diaryl Disulfides from Aryl Halides

Abstract: A highly porous metal–organic framework Cu3 BTC2 (copper(II)-benzene-1,3,5-tricarboxylate) that known as MOF-199 was synthesized, and characterized by common methods including, FT-IR, XRD, EDX, SEM and then used as an efficient and recyclable catalyst for the direct synthesis of symmetric organic disulfides. A variety of symmetric diaryl disulfides with high chemoselectivity can be obtained by domino reaction of aryl halides (and tosylates) and potassium 5-methyl-1,3,4-oxadiazole-2- thiolate, as the base and sulfur-transfer reagent, in the presence of MOF-199. Graphical Abstract: [Figure not available: see fulltext.]

A novel copper-catalyzed, one-pot synthesis of symmetric organic disulfides from alkyl and aryl halides: Potassium 5-methyl-1,3,4-oxadiazole-2-thiolate as a novel sulfur transfer reagent

A new method is reported for the synthesis of symmetric diaryl and dialkyl disulfides from aryl and alkyl halides in the presence of copper using potassium 5-methyl-1,3,4-oxadiazole-2-thiolate as the base, ligand, and sulfur-transfer reagent.

Addition of ArSSAr to carbon-carbon multiple bonds using electrochemistry

ArS(ArSSAr)+ (arylbis(arylthio)sulfonium ions), which were generated and accumulated by the electrochemical oxidation of diaryl disulfides (ArSSAr) in CH2Cl2 at -78 °C, reacted with alkenes to give the corresponding diaryl