87641-49-4

Upstream product

• 87641-48-3 (4S,5R)-5-[(1S,2R)-2-(4-Methoxy-benzyloxy)-1,3-dimethyl-but-3-enyl]-4-[(R)-1-(4-methoxy-benzyloxy)-propyl]-2,2,4-trimethyl-[1,3]dioxolane 
• 35784-67-9 1,2:5,6-di-O-isopropylidene-3-C-methyl-α-D-glucofuranose 
• 87641-45-0 (R)-2-{(4R,5S)-5-[(R)-1-(4-Methoxy-benzyloxy)-propyl]-2,2,5-trimethyl-[1,3]dioxolan-4-yl}-propionaldehyde 
• 98004-18-3 [(2S,3R)-3-((S)-1-{(4R,5S)-5-[(R)-1-(4-Methoxy-benzyloxy)-propyl]-2,2,5-trimethyl-[1,3]dioxolan-4-yl}-ethyl)-2-methyl-oxiranyl]-methanol 
• 98004-19-4 (4S,5R)-5-[(S)-1-((2R,3R)-3-Iodomethyl-3-methyl-oxiranyl)-ethyl]-4-[(R)-1-(4-methoxy-benzyloxy)-propyl]-2,2,4-trimethyl-[1,3]dioxolane 
• 87641-44-9 (2S,3R,4R,5R)-5-(4-Methoxy-benzyloxy)-2,4-dimethyl-heptane-1,3,4-triol 
• 53929-15-0 1-((3aR,5R,6S,6aR)-6-Methoxy-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethanol 
• 72353-13-0 3,6-dideoxy-1,2-O-isopropylidene-3-C-methyl-β-L-lyxohexofuranos-5-ulose 
• 53929-10-5 1-((3aR,5R,6S,6aR)-6-Methoxy-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethane-1,2-diol 
• 98049-26-4 (Z)-3,5,6,7,8-pentadeoxy-1,2-O-isopropylidene-3,5-di-C-methyl-β-L-lyxo-oct-5-enofuranose 
• 87641-36-9 3,6-dideoxy-1,2-O-isopropylidene-3-C-methyl-α-D-glycero-hex-3-enofuranos-5-ulose 
• 87641-32-5 1,2-O-isopropylidene-3-C-methyl-3-O-methyl-α-D-xylopentodialdo-1,4-furanose 
• 53929-09-2 (3aR,5R,6S,6aR)-5-(2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-methoxy-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 98003-95-3 (S)-2-{(4R,5S)-5-[(R)-1-(4-Methoxy-benzyloxy)-propyl]-2,2,5-trimethyl-[1,3]dioxolan-4-yl}-propan-1-ol 

Relevant academic research and scientific papers

Chiral Synthesis of Polyketide-derived Natural Products. Part 6. Chemical Correlation of Chiral Synthons, Derived from D-Glucose for the Synthesis of Erythromycin A, with Chemical Cleavage Products of the Natural Antibiotic

In order to prove unequivocally the structures and configurations of the two synthesized segments, (3) and (4), for the synthesis of erythromycin A (1) from D-glucose (2), chemical cleavage of dihydroerythronolide A (5) at the lactone and the 5,6-vicinal

Chiral Synthesis of Polyketide-derived Natural Products. Part 4. Synthesis of a Left-hand Segment with Six Consecutive Chiral Centres of Dihydroerythronolide A for the Total Synthesis of Erythromycin A from D-Glucose

For the purpose of the total synthesis of erythromycin A (1) from D-glucose (2) with the aid of stereochemical control in acyclic systems and p-methoxyphenylmethyl (MPM) protection, (2R,3S,4S,5R,6R,7R)-1-hydroxy-5,6-isopropylidenedioxy-3,7-bis(4-methoxybe