87654-96-4Relevant academic research and scientific papers
Preparation and Nuclear Magnetic Resonance Studies of Pentacoordinated Phosphorus Compounds Containing Hexafluoroisopropoxy Groups
Denney, Donald, B.,Denney, Dorothy Z.,Hammond, Philip J.,Liu, Lun-Tsu,Wang, Yu-Pin
, p. 2159 - 2164 (1983)
The reaction of 1,1,1,3,3,3-hexafluoroisopropyl benzenesulfenate (7) with tris(1,1,1,3,3,3-hexafluoroisopropyl)phosphite (8) yielded tetrakis(1,1,1,3,3,3-hexafluoroisopropoxy)(phenylthio)phosphorane (9).Variable-temperature 19F NMR studies of 9 show that
SOME CHEMISTRY OF 2,8-DIOXA-5-AZA-1-PHOSPHABICYCLOCTANE AND 2,10-DIOXA-6-AZA-1-PHOSPHABICYCLO DECANE. FURTHER EVIDENCE FOR THE BIPHILIC INSERTION MECHANISM >
Denney, Donald B.,Denney, Dorothy Z.,Hammond, Philip J.,Huang, Chialang,Liu, Lun-Tsu,Tseng, Kuo-Shu
, p. 281 - 292 (2007/10/02)
2,8-Dioxa-5-aza-1-phosphabicyclo octane, 1, and 2,10-dioxa-6-aza-1-phosphabicyclo decane, 2, both react with diethyl peroxide to give phosphoranes containing two ethoxy groups.The reactivities of 1 and 2 towards diethyl peroxide are very dif
