876665-57-5

Basic information

• Product Name: [(η-C5H5)2Mo(tropolonato)](tosyl)
• CAS NO: 876665-57-5
• Molecular Weight: 518.442
• Mol File: 876665-57-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η-C5H5)2Mo(tropolonato)](tosyl)(CAS DataBase Reference)
• NIST Chemistry Reference: [(η-C5H5)2Mo(tropolonato)](tosyl)(876665-57-5)
• EPA Substance Registry System: [(η-C5H5)2Mo(tropolonato)](tosyl)(876665-57-5)

Safety Data

• Hazardous Substances Data: 876665-57-5(Hazardous Substances Data)

Upstream product

• 533-75-5 2-hydroxy-2,4,6-cycloheptatrien-1-one 

Relevant articles and documents

Synthesis of molybdenocene(IV) and tungstenocene(IV) tropolonato complexes: Its derivative containing calix[4]arene moiety

The cationic di-μ-hydroxo dinuclear complexes of molybdenocene and tungstenocene [Cp2M(μ-OH)2MCp2]+ (Cp = η-C5H5; M = Mo or W) react with tropolone to afford corresponding tropolonato complexes [Cp2M(trop)]+ (trop = C7H5O2). The products were investigated by IR, 1H NMR, and 13C NMR spectroscopy as well as by X-ray crystallography (M = W). The structure shows that the central metal is surrounded by a distorted tetrahedral array of the two centers of cyclopentadienyl ligands and the two oxygen atoms of tropolonato ligand. The reaction has been extended to the synthesis of calix[4]arene receptor functionalized at the 1,3-positions of the upper rim with two tropolonato-molybdenocene centers.