87668-70-0Relevant articles and documents
Regioselective conversion of anhydro sugars into halohydrins and X-ray study
Shah, Syed Tasadaque A.,Abdel-Jalil, Raid J.,Khan, Khalid M.,Heinrich, Angelica M.,Richter, Markus,Voelter, Wolfgang
, p. 337 - 340 (2004)
A rapid, easy, regio- and stereoselective synthesis of 3-halo-3-deoxy sugars using titanium tetrahalides is described. To fully confirm the stereochemistry of the synthetic products, the X-ray structure of benzyl 3-chloro-3-deoxy-β-L-xylopyranoside was de
A Regioselective Synthesis of 3-Chloro-3-deoxy Sugars by Dichlorobis(benzonitrile)palladium (II)
Afza, Nighat,Malik, Abdul,Voelter, Wolfgang
, p. 1349 - 1351 (2007/10/02)
A regioselective synthesis of 3-chloro-3-deoxy sugars (6)-(10) has been achieved by trans-diaxial cleavage of the oxiran ring in 2,3-anhydro sugars (1)-(5) with dichlorobis(benzonitrile)palladium (II).The complex does not cause epoxide migration and may b