876748-82-2

Upstream product

• 876748-95-7 (1R,2R,6R,7R,8R,9S)-9-(3-Hydroxy-propyl)-6-isopropyl-3-methyl-12-oxa-tricyclo[6.3.1.0^2,7]dodec-3-en-10-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 876748-81-1 (1R,2R,6R,7R,8R,9S)-9-Allyl-6-isopropyl-3-methyl-12-oxa-tricyclo[6.3.1.0^2,7]dodec-3-en-10-one 
• 876748-94-6 (1R,2R,6R,7R,8R,9R)-9-allyl-6-isopropyl-3-methyl-12-oxatricyclo[6.3.1.0^2,7]dodec-3-en-10-one 
• 672904-59-5 (1S,2R,3R,7R,8S)-10-Hydroxy-3-isopropyl-6-methyl-12-oxa-tricyclo[6.3.1.0^2,7]dodeca-5,9-diene-9-carboxylic acid methyl ester 
• 876748-93-5 methyl (1R,2R,3R,7R,8S,11R)-11-allyl-10-hydroxy-3-isopropyl-6-methyl-12-oxatricyclo[6.3.1.0^2,7]dodeca-5,9-diene-9-carboxylate 

Downstream Products

• 876748-79-7 Acetic acid (1R,2S,3R,6R,7R,8R,9S)-9-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-6-isopropyl-3-methyl-11-oxo-10,13-dioxa-tricyclo[6.4.1.0^2,7]tridec-3-yl ester 
• 876748-80-0 Acetic acid (1R,2S,3R,6R,7R,8R,9S)-9-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-6-isopropyl-3-methyl-10-oxo-12-oxa-tricyclo[6.3.1.0^2,7]dodec-3-yl ester 
• 876748-97-9 (1R,2S,3R,6R,7R,8R,9S)-9-[3-(tert-Butyl-diphenyl-silanyloxy)-propyl]-3-hydroxy-6-isopropyl-3-methyl-12-oxa-tricyclo[6.3.1.0^2,7]dodecan-10-one 
• 876748-96-8 (1R,2S,3S,4S,6R,7R,8R,9S)-4-Bromo-9-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3-hydroxy-6-isopropyl-3-methyl-12-oxa-tricyclo[6.3.1.0^2,7]dodecan-10-one 

Relevant academic research and scientific papers

A general route toward the synthesis of the cladiellin skeleton utilizing a SmI2-mediated cyclization

An efficient synthesis of the cladiellin skeleton is reported utilizing methods that were previously developed in this laboratory. The approach is based on a SmI2-mediated cyclization reaction for the construction of the oxacyclononane unit. A