87696-27-3Relevant academic research and scientific papers
Selective Tosylations of 3,6-Anhydrohexofuranosides with gluco, manno, and gulo Configuration
Koell, Peter,Komander, Herbert
, p. 1332 - 1344 (2007/10/02)
Selective monotosylation of methyl 3,6-anhydro-α-D-mannofuranoside (1a) preferentially yields the 5-O-tosylate 1e which opens via nucleophilic substitution access to β-L-gulo derivatives 2 by inversion of configuration at C-5.Analogously reaction of the d
