87696-42-2

Basic information

• Product Name: Oxazole, 2-(5-hexenyloxy)-4,5-diphenyl-
• CAS NO: 87696-42-2
• Molecular Formula: C21H21NO2
• Molecular Weight: 319.403
• Mol File: 87696-42-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Oxazole, 2-(5-hexenyloxy)-4,5-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxazole, 2-(5-hexenyloxy)-4,5-diphenyl-(87696-42-2)
• EPA Substance Registry System: Oxazole, 2-(5-hexenyloxy)-4,5-diphenyl-(87696-42-2)

Safety Data

• Hazardous Substances Data: 87696-42-2(Hazardous Substances Data)

Upstream product

• 821-41-0 5-Hexen-1-ol 
• 49656-04-4 2-Chlor-4,5-diphenyl-oxazol 

Downstream Products

• 87696-39-7 4,5-diphenyl-3-furfuryl-4-oxazolin-2-one 
• 67909-78-8 3-allyl-4,5-diphenyl-4-oxazolin-2-one 
• 5014-83-5 4,5-diphenyloxazol-2-one 

Relevant articles and documents

Studies Dealing with the Aza-Claisen Rearrangement of 2-Allyloxy-Substituted Oxazoles

The scope of the thermal -sigmatropic rearrangement of a number of 2-allyloxy-substituted 4,5-diphenyloxazoles has been examined.These systems undergo a facile aza-Claisen rearrangement to give 3-allyl-substituted 4,5-diphenyl-4-oxazolin-2-ones.In contrast to the thermal results, irradiation of the 2-allyloxy- or benzyloxy-substituted oxazole gave rise to a mixture of 3- and 5-substituted oxazolinones.The photolysis proceeds via C-O bond scission to generate a radical pair which subsequently recombines to produce the mixture of oxazolinones.A series of related oxazoles was prepared in which the heterocyclic ring and the ? bond are connected by an alkoxy side chain.All attempts to induce an intramolecular Diels-Alder reaction failed.The only product that could be obtained corresponds to that derived from an intramolecular ene reaction.The excited-state behavior of several 2- and 5-allyloxy-substituted oxazoles was also studied.The rationale for the difference in thermal and photochemical behavior is discussed.