87707-11-7

Basic information

• Product Name: benzo[h]quinolin-7-ol
• CAS NO: 87707-11-7
• Molecular Formula: C₁₃H₉NO
• Molecular Weight: 195.2167
• Mol File: 87707-11-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 420.6°C at 760 mmHg
• Flash Point: 208.2°C
• Density: 1.307g/cm³
• Vapor Pressure: 1.13E-07mmHg at 25°C
• Refractive Index: 1.767
• CAS DataBase Reference: benzo[h]quinolin-7-ol(CAS DataBase Reference)
• NIST Chemistry Reference: benzo[h]quinolin-7-ol(87707-11-7)
• EPA Substance Registry System: benzo[h]quinolin-7-ol(87707-11-7)

Safety Data

• Hazardous Substances Data: 87707-11-7(Hazardous Substances Data)

Upstream product

• 106274-19-5 7-aminobenzoquinoline 
• 13019-32-4 7-bromo-8-hydroxyquinoline 
• 853953-71-6 toluene-4-sulfonic acid 7-bromo-quinolin-8-yl ester 
• 865836-98-2 C₁₃H₉NO 

Downstream Products

• 87707-10-6 trans-7,8-dihydro-7,8-dihydroxybenzoquinoline 
• 113163-22-7 7β,8α-dihydroxy-9α,10α-epoxy-7,8,9,10-tetrahydrobenzoquinoline 
• 113163-22-7 7β,8α-dihydroxy-9β,10β-epoxy-7,8,9,10-tetrahydrobenzoquinoline 

Relevant articles and documents

Mechanism of C-F reductive elimination from palladium(IV) fluorides

The first systematic mechanism study of C-F reductive elimination from a transition metal complex is described. C-F bond formation from three different Pd(IV) fluoride complexes was mechanistically evaluated. The experimental data suggest that reductive elimination occurs from cationic Pd(IV) fluoride complexes via a dissociative mechanism. The ancillary pyridyl-sulfonamide ligand plays a crucial role for C-F reductive elimination, likely due to a K 3 coordination mode, in which an oxygen atom of the sulfonyl group coordinates to Pd. The pyridyl-sulfonamide can support Pd(IV) and has the appropriate geometry and electronic structure to induce reductive elimination.