87707-45-7

Upstream product

• 87707-44-6 (5R*,9S*)-2-benzoyl-9-bromo-5,9-dimethylthiazolo<5,4-f>morphan 
• 618-32-6 Benzoyl bromide 
• 87707-38-8 7-(2-aminoethyl)-4,7-dihydro-6,7-dimethylbenzothiazole 
• 87707-40-2 (5R*,5aR*,8aS*)-5-bromo-4,5,5a,7,8,8a-hexahydro-5a,8a-dimethyl-6H-thiazolo<5,4-e>indole dihydrobromide 
• 87707-29-7 2-(2-Hydroxy-3,3-dimethyl-6-oxo-cyclohex-1-enyl)-isothiourea; hydrobromide 
• 87707-35-5 7-cyanomethyl-4,5,6,7-tetrahydro-7-hydroxy-6,6-dimethylbenzothiazole 
• 87707-36-6 7-(2-Amino-ethyl)-6,6-dimethyl-4,5,6,7-tetrahydro-benzothiazol-7-ol 
• 87707-42-4 (2bR,6bR,6cS)-6b,6c-Dimethyl-1,2,2b,3,6b,6c-hexahydro-6-thia-2a,4-diaza-cyclopropa[cd]-as-indacene 
• 87707-33-3 2-chloro-4,5,6,7-tetrahydro-6,6-dimethyl-7-oxobenzothiazole 
• 87707-28-6 2-amino-4,5,6,7-tetrahydro-6,6-dimethyl-7-oxobenzothiazole 
• 87707-37-7 2-[6,6-Dimethyl-5,6-dihydro-4H-benzothiazol-(7E)-ylidene]-ethylamine 
• 87707-34-4 4,5,6,7-tetrahydro-6,6-dimethyl-7-oxobenzothiazole 
• 87707-27-5 2-bromo-4,4-dimethyl-1,3-cyclohexanedione 

Relevant academic research and scientific papers

Thiazole analogs of benzomorphans. II. Synthesis of novel thiazolo[5,4-f]morphans

Cyanomethylation of 4,5,6,7-tetrahydro-6,6-dimethyl-7-oxobenzothiazole (VII), which was prepared from 4,4-dimethyl-1,3-cyclohexanedione (I) in several steps, afforded the cyano alcohol (VIII). Compound VIII was treated with lithium aluminium hydride and t