877123-14-3Relevant academic research and scientific papers
Synthesis, characterization, and x-ray crystal structure of a gallium monohydroxide and a hetero-bimetallic gallium zirconium oxide
Singh, Sanjay,Jancik, Vojtech,Roesky, Herbert W.,Herbst-Irmer, Regine
, p. 949 - 951 (2006)
A monomeric hydroxide of gallium, LGa(Me)OH, containing terminal hydroxide and methyl groups was prepared by the hydrolysis of LGa(Me)Cl in the presence of N-heterocyclic carbene and water [L = HC{(CMe)(2,6-i-Pr2C 6H3N)}2] in high yield and in a pure form. LGa(Me)OH was used as a synthon to assemble the first hetero-bimetallic compound with a Ga-O-Zr core, [(LGaMe)-(Cp2ZrMe)](μ-O).
