877174-89-5

Basic information

• Product Name: Silanamine, 1-chloro-N-(2,6-dimethylphenyl)-1,1-dimethyl-N-(trimethylsilyl)-
• CAS NO: 877174-89-5
• Molecular Formula: C13H24ClNSi2
• Molecular Weight: 285.964
• Mol File: 877174-89-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silanamine, 1-chloro-N-(2,6-dimethylphenyl)-1,1-dimethyl-N-(trimethylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silanamine, 1-chloro-N-(2,6-dimethylphenyl)-1,1-dimethyl-N-(trimethylsilyl)-(877174-89-5)
• EPA Substance Registry System: Silanamine, 1-chloro-N-(2,6-dimethylphenyl)-1,1-dimethyl-N-(trimethylsilyl)-(877174-89-5)

Safety Data

• Hazardous Substances Data: 877174-89-5(Hazardous Substances Data)

Upstream product

• 69563-03-7 N-(2,6-dimethylphenyl)-N-trimethylsilylamine 
• 75-78-5 dimethylsilicon dichloride 
• 87-62-7 2,6-dimethylaniline 

Relevant articles and documents

N-bonded monosilanols: Synthesis and characterization of ArN(SiMe 3) SiMe2Cl and ArN(SiMe3)SiMe2OH (Ar = C6H5, 2,6-Me2C6H3, 2,6-iPr2C6H3)

By the use of aniline and the sterically hindered aromatic primary amines, 2,6-Me2C6H3NH2 and 2,6-iPr 2C6H3NH2, N-bonded monochlorosilanes, ArN(SiMe3)SiMe2Cl [Ar = C 6H5 (1a), Ar = 2,6-Me2C6H 3 (1b) and Ar = 2,6-iPr2C6H3 (1c)] have been prepared by a sequential deprotonation at the nitrogen followed by reaction with silyl chlorides. Hydrolysis of the N-bonded monochlorosilanes afforded the N-bonded monosilanols ArN(SiMe3)SiMe2OH [Ar = C6H5 (2a), Ar = 2,6-Me2C6H 3 (2b) and Ar = 2,6-iPr2C6H3 (2c)]. The X-ray crystal structure of le reveals a positional disorder of the Cl and CH3 substituents on silicon. The X-ray crystal structure of 2c shows that it is involved in an intermolecular O-H...O hydrogen bonding in the solid state to afford a dimeric structure containing the O2H 2 ring. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.