877177-87-2

Basic information

• Product Name: 4H-1-Benzopyran-4-one, 7-methoxy-3-(3-methoxyphenyl)-
• CAS NO: 877177-87-2
• Molecular Formula: C17H14O4
• Molecular Weight: 282.296
• Mol File: 877177-87-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4H-1-Benzopyran-4-one, 7-methoxy-3-(3-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4H-1-Benzopyran-4-one, 7-methoxy-3-(3-methoxyphenyl)-(877177-87-2)
• EPA Substance Registry System: 4H-1-Benzopyran-4-one, 7-methoxy-3-(3-methoxyphenyl)-(877177-87-2)

Safety Data

• Hazardous Substances Data: 877177-87-2(Hazardous Substances Data)

Upstream product

• 139256-06-7 7-hydroxy-3-(3-methoxyphenyl)-4H-chromen-4-one 
• 77-78-1 dimethyl sulfate 
• 4637-24-5 N,N-dimethyl-formamide dimethyl acetal 
• 89019-83-0 1-(2,4-dihydroxyphenyl)-2-(3-methoxyphenyl)ethanone 
• 108-46-3 recorcinol 
• 1798-09-0 m-methoxyphenylacetic acid 

Downstream Products

• 877177-88-3 7-Methoxy-3-(3-methoxy-phenyl)-chroman-4-one 

Relevant articles and documents

Enantioselective Synthesis of Isoflavanones and Pterocarpans through a RuII-Catalyzed ATH-DKR of Isoflavones

Noyori-Ikariya RuII complexes promoted the one-pot C=C/C=O bonds reduction of isoflavones using sodium formate as the hydrogen source through Asymmetric Transfer Hydrogenation-Dynamic Kinetic Resolution (ATH-DKR). Due to the neutral conditions employed, isoflavones with different substituents at the 2’-position of B-ring (H, OH, OMe and Br) were successfully reduced. Ten cis-3-phenylchroman-4-ols were selectively obtained (>20 : 1 dr) in good yields (up to 86 %) and excellent enantioselectivities (up to >99 : 1 er). The synthetic applications of these chiral compounds were also demonstrated. Enantioenriched isoflavanones were obtained under mild metal-free oxidation of the cis-3-phenylchroman-4-ols while pterocarpans were synthesized by two strategies: an acid-catalyzed cyclization and a novel approach based on a Pd-catalyzed C?O intramolecular cross-coupling reaction.