877384-26-4

Basic information

• Product Name: Carbamic acid, ethyl[(1S)-1-methyl-2-oxo-2-phenylethyl]-, phenylmethyl ester
• CAS NO: 877384-26-4
• Molecular Formula: C19H21NO3
• Molecular Weight: 311.381
• Mol File: 877384-26-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbamic acid, ethyl[(1S)-1-methyl-2-oxo-2-phenylethyl]-, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, ethyl[(1S)-1-methyl-2-oxo-2-phenylethyl]-, phenylmethyl ester(877384-26-4)
• EPA Substance Registry System: Carbamic acid, ethyl[(1S)-1-methyl-2-oxo-2-phenylethyl]-, phenylmethyl ester(877384-26-4)

Safety Data

• Hazardous Substances Data: 877384-26-4(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 

Downstream Products

• 37573-41-4 (1S,2S)-2(N-Ethylamino)-1-phenyl-1-propanol 
• 37589-40-5 2-(ethylamino)-1-phenyl-1-propanol 

Relevant articles and documents

Highly diastereoselective catalytic Meerwein-Ponndorf-Verley reductions

Very practical synthesis of ephedrine analogues in high yields and enantiopurity was realized by a highly diastereoselective Meerwein-Ponndorf- Verley (MPV) reduction of protected α-amino aromatic ketones using catalytic aluminum isopropoxide. The high anti selectivity resulted from the chelation of the nitrogen anion to the aluminum. In contrast, high syn selectivity was obtained with α-alkoxy ketones and other compounds via Felkin-Ahn control.