877458-01-0Relevant academic research and scientific papers
Facile synthesis of trifluoromethyl-substituted enynes: Remarkable reactivity and stereoselectivity of tributyl(3,3,3-trifluoropropynyl)stannane in carbostannylation of alkynes
Shimizu, Masaki,Jiang, Guofang,Murai, Masahito,Takeda, Youhei,Nakao, Yoshiaki,Hiyama, Tamejiro,Shirakawa, Eiji
, p. 1700 - 1701 (2007/10/03)
Carbostannylation of alkynes with tributyl(3,3,3-trifluoropropynyl)stannane is found to proceed at room temperature in a syn-manner, giving rise to the corresponding CF3-substituted enynes as a single stereoisomer in good yields. Both terminal
