87760-36-9

Upstream product

• 61198-91-2 2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl-(1→4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl bromide 
• 91280-47-6 2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl-(1->4)-1,2,3,6-tetra-O-benzoyl-D-glucopyranose 

Downstream Products

• 1316725-14-0 C₅₄H₄₅NO₁₆ 
• 97523-61-0 cyclohexyl 3,6-di-O-benzoyl-2-(benzoyloximino)-4-O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-α-D-arabino-hexopyranoside 
• 97523-51-8 cyclohexyl 3,6-di-O-benzoyl-2-(benzoyloximino)-4-O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-β-D-arabino-hexopyranoside 
• 97523-60-9 benzyl O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-(1<*>4)-3,6-di-O-benzoyl-2-(benzoyloxyimino)-α-D-arabinohexopyranoside 
• 97523-50-7 benzyl 3,6-di-O-benzoyl-2-(benzoyloximino)-4-O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-β-D-arabino-hexopyranoside 
• 97523-59-6 methyl 3,6-di-O-benzoyl-2-(benzoyloximino)-4-O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-α-D-arabino-hexopyranoside 
• 97523-49-4 methyl 3,6-di-O-benzoyl-2-(benzoyloximino)-4-O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-β-D-arabino-hexopyranoside 
• 97523-39-2 3,6-di-O-benzoyl-2-(benzoyloximino)-4-O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-α-D-arabino-hexopyranosyl bromide 
• 97523-41-6 3,6-di-O-benzoyl-4-O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-1,5-anhydro-D-fructose O-benzoyloxime 
• 97523-62-1 methyl N-acetylhexa-O-benzoyl-α-D-lactosaminide 
• 97523-52-9 methyl 2-acetamido-3,6-di-O-benzoyl-4-O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-2-deoxy-β-D-mannopyranoside 
• 97523-64-3 C₅₇H₅₂O₁₇ 
• 97523-65-4 C₅₇H₅₂O₁₇ 
• 97523-58-5 methyl hexa-O-benzoyl-α-D-lactosuloside oxime 

Relevant academic research and scientific papers

A method for the syntheses of Enopyranosides

Sodium hydride (NaH) in hexamethylphosphoric triamide (HMPA) has been introduced as an economical and efficient reagent towards the creation of 1, 2- or 5, 6-enopyranosides from the corresponding halogenated or tosylated pyranosides. NaH/HMPA has several advantages compared to NaH/DMF: elimination products are produced in high yields even from sterically-hindered halides as well as tosylates. 2009 Bentham Science Publishers Ltd.

Sodium hydride/hexamethylphosphoric triamide: A new and efficient reagent towards the synthesis of protected 1,2- and 5,6-enopyranosides

A new method for the elimination of hydrogen halides and p-toluenesulfonic acid from sugar moieties using sodium hydride (NaH) in hexamethylphosphoric triamide (HMPA) at room temperature is reported. NaH/HMPA has several advantages compared to NaH/DMF: elimination products are produced in high yields even from sterically hindered starting materials, and not only from halides, but also tosylates.

Disaccharide-Derived 2-Oxo- and 2-Oximinoglycosyl Bromides: Novel, Conveniently Accessible Building Blocks for the Expedient Construction of Oligosaccharides with α-D-Glucosamine, β-D-Mannose, and β-D-Mannosamine as Constituent Sugars

A concise, practical, large-scale adaptable approach has been developed for the transformation of bulk disaccharides such as lactose, maltose, and cellobiose into disaccharide building blocks suitably functionalized for direct glycobiosylation, i.e., benz