87763-68-6Relevant academic research and scientific papers
Chelation Control of Enolate Geometry. Acyclic Diastereoselection via the Enolate Claisen Rearrangement
Burke, Steven D.,Fobare, William F.,Pacofsky, Gregory J.
, p. 5221 - 5228 (2007/10/02)
The Ireland-Claisen rearrangements of a variety of O-protected allylic glycolate esters are described.Vicinal diastereoselectivities ranging from 7.2:1 to >20:1 were observed, indicating that chelation control of enolate geometry is operational in the con
