877671-93-7Relevant academic research and scientific papers
Reaction of δ-silyl-γ,δ-epoxy-α,β-unsaturated acylsilanes with cyanide ion: Possibility of the formation of silicate intermediate in anion-induced ring opening of epoxysilanes
Tanaka, Koudai,Masu, Hyuma,Yamaguchi, Kentaro,Takeda, Kei
, p. 6429 - 6432 (2005)
Reaction of trans- and cis-δ-silyl-γ,δ-epoxy-α, β-unsaturated acylsilanes 1 and 9 with cyanide ion in the presence of an electrophile affords double Brook rearrangement products 10 in an E/Z ratio depending on the cis/trans geometry of the epoxysilanes.
