877773-38-1

Basic information

• Product Name: S,S-2,6-bis(1,1-diMethylethyl)-2,3,5,6-tetrahydro-1H-IMidazo[1,2-a]iMidazole
• Synonyms: (2S,6S)-2,6-Di-tert-butyl-2,3,5,6-tetrahydro-1H-imidazo[1,2-a]imidazole;(2S,6S)-2,6-Bis(1,1-dimethylethyl)-2,3,5,6-tetrahydro-1H-Imidazo[1,2-a]imidazole;(2S,6S)-2,6-Bis(1,1-dimethylethyl)-2,3,5,6-tetrahydro-1Himidazo[ 1,2-a]imidazole,99%e.e.;S,S-2,6-bis(1,1-diMethylethyl)-2,3,5,6-tetrahydro-1H-IMidazo[1,2-a]iMidazole;1H-IMidazo[1,2-a]iMidazole,2,6-bis(1,1-diMethylethyl)-2,3,5,6-tetrahydro-,(2S,6S)-
• CAS NO: 877773-38-1
• Molecular Formula: C13H25N3
• Molecular Weight: 223.3577
• Mol File: 877773-38-1.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 285.484 °C at 760 mmHg
• Flash Point: 126.457 °C
• Appearance: /
• Density: 1.061 g/cm³
• PKA: 10.09±0.70(Predicted)
• CAS DataBase Reference: S,S-2,6-bis(1,1-diMethylethyl)-2,3,5,6-tetrahydro-1H-IMidazo[1,2-a]iMidazole(CAS DataBase Reference)
• NIST Chemistry Reference: S,S-2,6-bis(1,1-diMethylethyl)-2,3,5,6-tetrahydro-1H-IMidazo[1,2-a]iMidazole(877773-38-1)
• EPA Substance Registry System: S,S-2,6-bis(1,1-diMethylethyl)-2,3,5,6-tetrahydro-1H-IMidazo[1,2-a]iMidazole(877773-38-1)

Safety Data

• Hazardous Substances Data: 877773-38-1(Hazardous Substances Data)

Usage

Chemical Properties

Solid

Upstream product

• 1173050-17-3 C₁₃H₂₆N₃⁽¹⁺⁾*I^(1-) 
• 216220-08-5 (S)-N-(p-toluenesulfonyl)-2-tert-butylaziridine 
• 112245-13-3 (S)-tert-leucinol 
• 877773-35-8 C₂₆H₄₁N₃O₄S₂ 
• 2314-48-9 (S,S)-dimethyl trithiocarbonate 

Relevant articles and documents

Guanidine–Copper Complex Catalyzed Allylic Borylation for the Enantioconvergent Synthesis of Tertiary Cyclic Allylboronates

An enantioconvergent synthesis of chiral cyclic allylboronates from racemic allylic bromides was achieved by using a guanidine–copper catalyst. The allylboronates were obtained with high γ/α regioselectivities (up to 99:1) and enantioselectivities (up to 99 % ee), and could be further transformed into diverse functionalized allylic compounds without erosion of optical purity. Experimental and DFT mechanistic studies support an SN2′ borylation process catalyzed by a monodentate guanidine–copper(I) complex that proceeds through a special direct enantioconvergent transformation mechanism.