87794-75-0Relevant academic research and scientific papers
METALLORGANISCHE LEWIS-SAEUREN; METALLKOMPLEXE MIT SCHWACH KOORDINIERTEN ANIONISCHEN LIGANDEN. XII. REAKTIONEN VON (?-C5H5)(CO)3MoX (X- = BF4-, PF6-, AsF6-, SbF6-) MIT METHYL-CARBONYL-KOMPLEXEN SOWIE MIT COBALTOCEN, NICKELOCEN UND (?-C5H5)Co(CO)2. STRUKTUR VON...
Suenkel, Karlheinz,Nagel, Ulrich,Beck, Wolfgang
, p. 227 - 244 (2007/10/02)
The acyl-bridged complexes 2-, η2-COCH2Ph)Mo(CO)2(?-C5H5)>+ BF4- (2b),2-, η1-COCH3)Mo(CO)3(?-C5H5)>+ SbF6- (4) besides other products have been obtained from the reaction of (?-C5H5)(CO)3MoX (X-= BF4-, SbF6-) with (?-C5H5)(CO)3MoCH2Ph and (?-C5H5)(CO)2FeCH3, respectively.The X-ray structure of 4 has been determinated.Hydrine and methyl transfer occurs in the reaction of (?-C5H5)(CO)3MoFBF3 with (CO)5MCH3 (M = Mn, Re) to give 2H>+ BF4-, (?-C5H5)(CO)3MoCH3 and (CO)5MFBF3. (?-C5H5)(CO)3MoFBF3 reacts with (?-C5H5)Co(CO)2 to give a 1:1 adduct, whereas with M(?-C5H5)2 (M = Ni, Co) redox reactions have been observed.
