87797-56-6Relevant academic research and scientific papers
Nitroxide Radicals. Part 21. Spontaneous Decomposition of N-Aryl 1- and 2-Naphthyl Nitroxides
Forrester, Alexander R.,Fullerton, Joseph D.,McConnachie, Gordon
, p. 1759 - 1764 (2007/10/02)
N-Aryl 1-naphthyl nitroxides self-react in solution to give the corresponding secondary amines and N-aryl-1,4-naphthoquinone imines.When reaction at the 4-naphthyl position is hindered by substituents benzoquinone imines are also produced.N-Phenyl 2-naphthyl nitroxide under similar conditions gives the corresponding amine and 2-phenylamino-1,4-naphthoquinone via a 1,2-naphthoquinone imine N-oxide intermediate.
Reactivity and Structure of N-Phenyl-1-naphthylamines and Related Compounds. Part 3. Reaction with Oxygen-centred Radicals
Forrester, Alexander R.,Fullerton, Joseph D.,McConnachie, Gordon
, p. 2711 - 2715 (2007/10/02)
Comparison is made between products obtained by oxidation of N-phenyl-1-naphthylamines and 1-naphthyl phenyl nitroxides with peroxyl radicals.It is concluded that oxidation of the amines does not proceed to a considerable extent via the nitroxides.Comparison is also made of products obtained from these amines and nitroxides by oxidation with Fremy's salt.
