878049-35-5

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 878049-30-0 (S)-(R)-1-Oxiranyl-pent-4-en-2-ol 
• 130481-49-1 (4S,6R)-4-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-6,7-epoxy-1-heptene 
• 130459-43-7 (4R,6R)-4-<oxy>-6,7-epoxyheptene 
• 2883-45-6 1, 6-heptadien-4-ol 
• 878049-29-7 4-Nitro-benzoic acid (S)-1-(R)-1-oxiranylmethyl-but-3-enyl ester 
• 878049-28-6 1-(oxiran-2-yl)pent-4-en-2-ol 
• 878049-23-1 (2R,4S)-4-(tert-Butyl-dimethyl-silanyloxy)-1-[2-((E)-styryl)-[1,3]dithian-2-yl]-hept-6-en-2-ol 
• 109-92-2 ethyl vinyl ether 

Downstream Products

• 878049-25-3 Acrylic acid (S)-1-{(R)-2-(1-ethoxy-ethoxy)-3-[2-((E)-styryl)-[1,3]dithian-2-yl]-propyl}-but-3-enyl ester 
• 878049-26-4 (S)-6-{(R)-2-(1-Ethoxy-ethoxy)-3-[2-((E)-styryl)-[1,3]dithian-2-yl]-propyl}-5,6-dihydro-pyran-2-one 
• 878049-33-3 (S)-6-{(R)-2-Hydroxy-3-[2-((E)-styryl)-[1,3]dithian-2-yl]-propyl}-5,6-dihydro-pyran-2-one 
• 878049-24-2 (4S,6R)-6-(1-Ethoxy-ethoxy)-7-[2-((E)-styryl)-[1,3]dithian-2-yl]-hept-1-en-4-ol 

Relevant academic research and scientific papers

Resolution of 2-silyloxy-1-oxiranyl-4-pentenes by HKR: Total synthesis of (5S,7R)-kurzilactone

Enantiomerically pure syn- and anti-2-silyloxy-1-oxiranyl-4-pentenes were prepared by using Jacobsen's hydrolytic kinetic resolution (HKR) method. A resolved epoxypentenol generated in this fashion was used in the total synthesis of (5S,7R)-kurzilactone b