87812-89-3Relevant academic research and scientific papers
A Simple Procedure to Prepare the Labile Stereoisomers of 5-Benzylidenepyrrolin-2-ones
Stachel, Hans-Dietrich,Poschenrieder, Hermann,Wiesend, Bruno
, p. 988 - 991 (2007/10/02)
The known Z-isomers of some N-unsubstituted 5-benzylidenepyrrolin-2-ones (2, 10, 12) change the configuration upon heating with oxalylchloride.Methanolysis of the intermediate imides (6, 8, 9) yields the corresponding E-isomers. - Key words: 5-Benzylidenepyrrolin-2-ones, 5-Benzylidenetetramic Acids, cis-trans Isomerisation
