878270-46-3Relevant academic research and scientific papers
Mechanistic studies on the stereoselective formation of β-mannosides from mannosyl iodides using α-deuterium kinetic isotope effects
El-Badri, Mohamed H.,Willenbring, Dan,Tantillo, Dean J.,Gervay-Hague, Jacquelyn
, p. 4663 - 4672 (2007)
(Chemical Equation Presented) Stereoselective synthesis of β-mannosides is one of the most challenging linkages to achieve in carbohydrate chemistry. Both the anomeric effect and the C2 axial substituent favor the formation of the axial glycoside (α-produ
Trifluoromethanesulfonic acid efficiently catalyzed the intramolecular glycosidation of 1-C-alkyl-D-hexopyranoses to form the anhydroketopyranoses having 6,8-dioxabicyclo[3.2.1]octane structures
Yamanoi, Takashi,Matsumura, Kazuhide,Matsuda, Sho,Oda, Yoshiki
, p. 2973 - 2977 (2007/10/03)
The intramolecular glycosidation of the 1-C-alkyl-D-hexopyranose derivatives to form the anhydroketopyranoses having 6,8-dioxabicyclo[3.2.1] octane structures was investigated. We synthesized several 1-C-alkyl-2,3,4-tri- O-benzyl-D-hexopyranoses and found
