878550-30-2

Upstream product

• 77-76-9 2,2-dimethoxy-propane 
• 878550-29-9 ((3aR,4R,5S,9aR)-4-(4-methoxybenzyloxy)-2,2-dimethyl-6-methyleneoctahydrocycloocta[d][1,3]dioxol-5-yloxy)(tert-butyl)-dimethylsilane 
• 878550-24-4 (1S,2R,3R,4R,5R)-3-(4-methoxybenzyloxy)-2-((tert-butyl)dimethylsilyloxy)-9-oxabicyclo[3.3.1]nonane-1,4-diol 
• 878550-28-8 (3aR,4R,5R,9aR)-4-(4-methoxybenzyloxy)-5-((tert-butyl)dimethylsilyloxy)-2,2-dimethylhexahydrocycloocta[d][1,3]dioxol-6(3aH)-one 

Relevant academic research and scientific papers

From common carbohydrates to enantiopure cyclooctane polyols and glycomimetics via deoxygenative zirconocene ring contraction

D-Arabinose and D-glucose are transformed into the identical vinyl furanoside, whose role is to serve as the precursor to enantiopure cyclooctadienone 6. The key steps of this relay involve a zirconocene-promoted ring contraction and [3,3] sigmatropic rea