878550-35-7

Upstream product

• 878550-34-6 (3aS,4R,5R,9aS)-4-(4-methoxybenzyloxy)-5-((tert-butyl)dimethylsilyloxy)-2,2-dimethylhexahydrocycloocta[d][1,3]dioxol-6(3aH)-one 
• 19493-09-5 Methylenetriphenylphosphorane 
• 77-76-9 2,2-dimethoxy-propane 
• 878550-23-3 (1R,2R,3R,4S,5S)-3-(4-methoxybenzyloxy)-2-((tert-butyl)dimethylsilyloxy)-9-oxabicyclo[3.3.1]nonane-1,4-diol 

Downstream Products

• 878550-36-8 ((3aS,4R,5S,6S,9aS)-4-(4-methoxybenzyloxy)-5-((tert-butyl)dimethylsilyloxy)-2,2-dimethyloctahydrocycloocta[d][1,3]dioxol-6-yl)methanol 
• 878550-37-9 ((3aS,4R,5S,6R,9aS)-4-(4-methoxybenzyloxy)-5-((tert-butyl)dimethylsilyloxy)-2,2-dimethyloctahydrocycloocta[d][1,3]dioxol-6-yl)methanol 

Relevant academic research and scientific papers

From common carbohydrates to enantiopure cyclooctane polyols and glycomimetics via deoxygenative zirconocene ring contraction

D-Arabinose and D-glucose are transformed into the identical vinyl furanoside, whose role is to serve as the precursor to enantiopure cyclooctadienone 6. The key steps of this relay involve a zirconocene-promoted ring contraction and [3,3] sigmatropic rea