87874-52-0Relevant academic research and scientific papers
REGIOSELECTIVITY OF THE ADDITION OF THIOLS TO 1-R-3-METHYLBICYCLOBUTANES
Vasin, V. A.,Razin, V. V.,Bolusheva, I. Yu.,Tanaseichuk, B. S.,Surmina, L. S.,Zefirov, N. S.
, p. 469 - 477 (2007/10/02)
The radical addition of thiols to 1-cyano-, 1-methoxycarbonyl-, 1-tert-butoxycarbonyl-, 1-acetyl-, and 1-benzoyl-3-methylbicyclobutanes was studied by GLC and PMR.In the case of thiophenol it was shown that the regioselectivity and relative reactivity of addition are determined by the polarity of the substituent.This is reflected in the satisfactory correlation between these values and the Taft ? constants.
