878800-58-9Relevant academic research and scientific papers
Palladium-catalyzed improved regio- and stereoselective O-glycosylation of D-glucal-derived β- And α-vinyl oxiranes
Reddy, Y. Suman,Lahiri, Rima,Vankar, Yashwant D.
, p. 4751 - 4761 (2012)
A Pd0-catalyzed glycosylation of D-glucal-derived vinyloxiranes as excellent glycosyl donors has been accomplished in a regio- and stereoselective manner. Various glycosyl acceptors upon reaction with vinyl oxiranes 1a and 1b produced the corre
Enantiopure cis- and trans-2,5-disubstituted-2,5-dihydrofurans from D-allal- and D-galactal-derived vinyl epoxides
Di Bussolo, Valeria,Princiotto, Salvatore,Bordoni, Vittorio,Martinelli,Favero, Lucilla,Crotti, Stefano,Uccello Barretta, Gloria,Balzano, Federica,Pineschi,Crotti
, p. 4425 - 4443 (2019/07/04)
Upon treatment with the metal enolates of methylene active compounds (dimethyl malonate and dibenzoylmethane) (C-nucleophiles) and benzyl carbamate (N-nucleophile), D-allal- and D-galactal-derived vinyl epoxides are stereoselectively transformed, in a sin
Stereoselective uncatalyzed synthesis of 2,3-unsaturated-4-N-substituted- β-O-glycosides by means of a new D-galactal-derived N-(mesyl)-aziridine
Di Bussolo, Valeria,Romano, Maria Rosaria,Favero, Lucilla,Pineschi, Mauro,Crotti, Paolo
, p. 1696 - 1699 (2007/10/03)
The reaction of the new D-galactal-derived allylic aziridine 1β with O-nucleophiles (alcohols and monosaccharides) affords, in a high to complete β-stereoselectivity, the corresponding 2,3-unsaturated-β-O-glycosides bearing a β-N-functionality at C(4).
