87882-26-6Relevant academic research and scientific papers
HYDROXY IRON(III) SPECIES STABILIZED WITH BULKY PORPHYRINS
Miyamoto, T. Ken,Tsuzuki, Seizi,Hasegawa, Tai,Sasaki, Yukiyoshi
, p. 1587 - 1588 (1983)
Stable hydroxy iron(III) complexes have been prepared in the use of bulky porphyrins, e.g., meso-tetrakis(3,5-di-t-butylphenyl)-porphyrin (Abbr.TBPP-H2) and meso-tetrakis(3,5-di-t-butyl-2-nitrophenyl)porphyrin (TBNPP-H2, 4 isomers).The stability of these
Synthesis and Properties of 5,10,15,20-Tetrakis(3,5-di-t-butyl-2-nitrophenyl)porphyrin: Conformational Stabilities of the Respective Atropisomers and Oxygenation Capabilities of the Iron(III) and Manganese(III) Complexes
Miyamoto, T. Ken,Takagi, Shigeru,Hasegawa, Tai,Tsuzuki, Seizi,Takahashi, Eitaro,et al.
, p. 1649 - 1660 (2007/10/02)
The synthesis and properties of new, bulky atropisomeric porphyrins are described.Four atropisomers of 5,10,15,20-tetrakis(3,5-di-t-butyl-2-nitrophenyl)porphyrins has been easily separated and purified by column chromatography.The isomers all have differe
