87902-24-7

Upstream product

• 110528-25-1 Benzoic acid (3aS,3bS,6aR,7aR)-2,2,3b-trimethyl-5-oxo-decahydro-cyclopenta[a]pentalen-3-yl ester 
• 335059-37-5 2-(hydroxymethyl)-3,3-dimethyl-5-methoxytetrahydrofuran 
• 78984-88-0 β,β-dimethyl-γ-(hydroxymethyl)-γ-butyrolactone 
• 110528-23-9 (3aS,4aR,7S,7aR)-6,6-Dimethyl-decahydro-1-oxa-cyclopenta[a]cyclopropa[g]pentalen-7-ol 
• 110528-14-8 5-Methoxy-3,3-dimethyl-tetrahydro-furan-2-carbaldehyde 
• 98360-86-2 (3α,3aα,6aβ,7aα)-2,3,3a,5,6,6a,7,7a-octahydro-3-hydroxy-2,2-dimethyl-1H-cyclopentapentalene 
• 98330-92-8 (3α,3aα,3bβ,6aβ,7aα)-2,3,3a,3b,6,6a,7,7a-octahydro-3,3b-dihydroxy-2,2-dimethyl-1H-cyclopentapentalene 
• 335059-36-4 2-<(benzyloxy)methyl>-5-hydroxy-3,3-dimethytetrahydrofuran 
• 98330-87-1 6-<5-methoxy-3,3-dimethyl-2-tetrahydrofuranyl>fulvene 
• 98330-86-0 2-<(benzyloxy)methyl>-5-methoxy-3,3-dimethyltetrahydrofuran 
• 110528-07-9 2-<(benzyloxy)methyl>-3,3-dimethyl-5-oxotetrahydrofuran 
• 98330-91-7 2,3-diaza-7-<2-hydroxy-3,3-dimethylhex-5-enylidene>bicyclo<2.2.1>hept-2-ene 
• 98330-90-6 2,3-diaza-7-<5-hydroxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>hept-2-ene 
• 98330-93-9 Benzoic acid (3aR,6aS,7aS)-2,2-dimethyl-5-oxo-2,3,3a,5,6,6a,7,7a-octahydro-1H-cyclopenta[a]pentalen-3-yl ester 

Downstream Products

• 80677-96-9 (+/-)-hypnophilin 

Relevant academic research and scientific papers

Intramolecular 1,3-Diyl Trapping Reactions. Total Synthesis of (+/-)-Hypnophilin and (+/-)-Coriolin. Formation of the Trans-Fused Bicyclooctane Ring System

The intramolecular 1,3-diyl trapping reaction served as the key step in total synthesis of (+/-)-coriolin (1) and the first total synthesis of (+/-)-hypnophilin (3).In the process, four of the required eight (coriolin) or six (hypnophilin) stereocenters w