87902-24-7

Basic information

• Product Name: Benzoic acid (3S,3aS,3bR,7aR)-2,2,3b-trimethyl-5-oxo-2,3,3a,3b,4,5,7,7a-octahydro-1H-cyclopenta[a]pentalen-3-yl ester
• CAS NO: 87902-24-7
• Molecular Weight: 324.42
• Mol File: 87902-24-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzoic acid (3S,3aS,3bR,7aR)-2,2,3b-trimethyl-5-oxo-2,3,3a,3b,4,5,7,7a-octahydro-1H-cyclopenta[a]pentalen-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (3S,3aS,3bR,7aR)-2,2,3b-trimethyl-5-oxo-2,3,3a,3b,4,5,7,7a-octahydro-1H-cyclopenta[a]pentalen-3-yl ester(87902-24-7)
• EPA Substance Registry System: Benzoic acid (3S,3aS,3bR,7aR)-2,2,3b-trimethyl-5-oxo-2,3,3a,3b,4,5,7,7a-octahydro-1H-cyclopenta[a]pentalen-3-yl ester(87902-24-7)

Safety Data

• Hazardous Substances Data: 87902-24-7(Hazardous Substances Data)

Upstream product

• 110528-25-1 Benzoic acid (3aS,3bS,6aR,7aR)-2,2,3b-trimethyl-5-oxo-decahydro-cyclopenta[a]pentalen-3-yl ester 
• 335059-37-5 2-(hydroxymethyl)-3,3-dimethyl-5-methoxytetrahydrofuran 
• 78984-88-0 β,β-dimethyl-γ-(hydroxymethyl)-γ-butyrolactone 
• 110528-18-2 N,N'-bis(methoxycarbonyl)-2,3-diaza-7-<5-methoxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>hept-5-ene 
• 110528-21-7 N,N'-bis(methoxycarbonyl)-2,3-diaza-7-<5-methoxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>heptane 
• 98330-89-3 N,N'-bis(methoxycarbonyl)-2,3-diaza-7-<5'-hydroxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>heptane 
• 110528-24-0 Benzoic acid (3aR,3bS,6aS,7aR)-3b-hydroxy-2,2-dimethyl-2,3,3a,3b,6,6a,7,7a-octahydro-1H-cyclopenta[a]pentalen-3-yl ester 
• 98330-93-9 Benzoic acid (3aR,6aS,7aS)-2,2-dimethyl-5-oxo-2,3,3a,5,6,6a,7,7a-octahydro-1H-cyclopenta[a]pentalen-3-yl ester 
• 98330-90-6 2,3-diaza-7-<5-hydroxy-3,3-dimethyl-2-tetrahydrofuranylidene>bicyclo<2.2.1>hept-2-ene 
• 98330-91-7 2,3-diaza-7-<2-hydroxy-3,3-dimethylhex-5-enylidene>bicyclo<2.2.1>hept-2-ene 
• 110528-07-9 2-<(benzyloxy)methyl>-3,3-dimethyl-5-oxotetrahydrofuran 
• 98330-86-0 2-<(benzyloxy)methyl>-5-methoxy-3,3-dimethyltetrahydrofuran 
• 98330-87-1 6-<5-methoxy-3,3-dimethyl-2-tetrahydrofuranyl>fulvene 
• 335059-36-4 2-<(benzyloxy)methyl>-5-hydroxy-3,3-dimethytetrahydrofuran 

Downstream Products

• 80677-96-9 (+/-)-hypnophilin 

Relevant articles and documents

Intramolecular 1,3-Diyl Trapping Reactions. Total Synthesis of (+/-)-Hypnophilin and (+/-)-Coriolin. Formation of the Trans-Fused Bicyclooctane Ring System

The intramolecular 1,3-diyl trapping reaction served as the key step in total synthesis of (+/-)-coriolin (1) and the first total synthesis of (+/-)-hypnophilin (3).In the process, four of the required eight (coriolin) or six (hypnophilin) stereocenters w

Chemistry of the Dianions of 3-Heteroatom-Substituted Cyclopent-2-en-1-ones: An Expedient Route to dl-Coriolin

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