879283-02-0Relevant articles and documents
Stereocontrolled synthesis of spiroketals via Ti(Oi-Pr)4- mediated kinetic spirocyclization of glycal epoxides with retention of configuration
Moilanen, Sirkka B.,Potuzak, Justin S.,Tan, Derek S.
, p. 1792 - 1793 (2006)
A Ti(Oi-Pr)4-mediated kinetic spiroketalization reaction has been developed for the stereocontrolled target- and diversity-oriented synthesis of spiroketals. In contrast to most existing methods for spiroketal synthesis, this reaction does not
Enantioselective synthesis of erythro-4-deoxyglycals as scaffolds for target- And diversity-oriented synthesis: New insights into glycal reactivity
Moilanen, Sirkka B.,Tan, Derek S.
, p. 798 - 803 (2007/10/03)
An efficient, enantioselective synthesis of eryithro-4-deoxygtycals has been developed using asymmetric aldehyde allylation and tungsten-catalyzed alkynol endo-cycloisomerization as the key steps. These versatile synthetic scaffolds have been elaborated t