879290-56-9Relevant academic research and scientific papers
A minimalist NMR approach for the structural revision of mucoxin
Yan, Jun,Garzan, Atefeh,Narayan, Radha S.,Vasileiou, Chrysoula,Borhan, Babak
supporting information; experimental part, p. 13749 - 13756 (2011/02/27)
In an attempt to revise the structural assignment of mucoxin, and faced with 64 diastereomeric possibilities, we resorted to the synthesis of truncated structures that contained the core stereochemical sites. Twelve stereochemical analogues were synthesiz
Synthesis of the proposed structure of mucoxin via regio- and stereoselective tetrahydrofuran ring-forming strategies
Narayan, Radha S.,Borhan, Babak
, p. 1416 - 1429 (2007/10/03)
An enantioselective total synthesis of the proposed structure of mucoxin (1) is described. Mucoxin, an annonaceous acetogenin isolated from bioactive leaf extracts of Rollinia mucosa, is the first acetogenin containing a hydroxylated trisubstituted tetrah
