879572-72-2

Upstream product

• 2065-66-9 methyl-triphenylphosphonium iodide 

Downstream Products

• 844699-00-9 (3S,5S,7aS,11′S)-3-(benzyloxymethyl)-5-hexyldecahydro-1H-pyrrolo[1,2-j]quinoline 
• 879572-67-5 (2S,5S,7aS,11aS)-3-(benzyloxymethyl)decahydro-1H-pyrrolo[1,2-j]quinoline-5-carbonitrile 
• 879572-79-9 3-benzyloxymethyl-2,3,7,7a,8,9,10,11-octahydro-1H-pyrrolo[2,1-j]quinoline 
• 879572-76-6 (2S,5S,6S)-tert-butyl 2-(benzyloxymethyl)-6-[3'-(tert-butyldiphenylsilanyloxy)propyl]-1-aza-spiro[4,5]decane-1-carboxylate 
• 879572-77-7 (2S,5S,6S)-tert-butyl 2-(benzyloxymethyl)-6-(3'-hydroxypropyl)-1-azaspiro[4,5]decane-1-carboxylate 
• 879572-78-8 (2S,5S,6S)-tert-butyl 2-(benzyloxymethyl)-6-(3'-oxo-propyl)-1-azaspiro[4,5]decane-1-carboxylate 
• 879572-75-5 (2S,5R,10S)-tert-butyl 5-(benzyloxymethyl)-10-[3'-(tert-butyldiphenylsilanyloxy)propyl]-1-azaspiro[4,5]dec-6-ene-1-carboxylate 

Relevant academic research and scientific papers

Divergent total synthesis of the tricyclic marine alkaloids lepadiformine, fasicularin, and isomers of polycitorols by reagent-controlled diastereoselective reductive amination

We describe a flexible and divergent route to the pyrrolo-/pyrido[1,2-j]quinoline frameworks of tricyclic marine alkaloids via a common intermediate formed by the ester-enolate Claisen rearrangement of a cyclic amino acid allylic ester. We have synthesize

Formal total synthesis of (-)-lepadiformine

A stereocontrolled approach to the preparation of the Weinreb intermediate 3 has been developed. The important features of this approach are the creation of stereogenic centers through a cyclic amino acid ester-enolate Claisen rearrangement and the use of