87974-55-8Relevant academic research and scientific papers
One-pot synthesis of 2-amino-3,4-dicyanopyridines from ketoximes and tetracyanoethylene via Cu(I)-catalyzed cyclization
Han, Ziwei,Lv, Jianguang,Zhang, Jianmin
supporting information, p. 2162 - 2168 (2019/02/25)
A novel approach to 2-amino-3,4-dicyanopyridines has been discovered from Cu(I)-catalyzed cyclizations of simple and easily available ketoximes and tetracyanoethylene (TCNE). The complexed radical mechanism involves cleavage of several O[sbnd]H/N[sbnd]O/C
Copper-catalyzed synthesis of oxime ethers from iminoxy radical (C[dbnd]N–O[rad]) and maleimides via radical addition
Han, Ziwei,Shen, Subo,Zheng, Feng,Hu, Han,Zhang, Jianmin,Zhu, Shizheng
supporting information, (2019/09/30)
An efficient Cu(II)-catalyzed radical addition of maleimides has been achieved. The identified copper catalyst enables the formation of oxime radicals (N–O[rad]) by cleaving the O–H bond in ketoximes, followed by the radical addition to N-substituted male
Gas-phase acidities of acetophenone oximes. Substituent effect and solvent effects
Badal, Mizanur Rahman,Mishima, Masaaki
experimental part, p. 58 - 65 (2010/03/25)
Gas-phase acidities (GA) of ring-substituted (E)-acetophenone oximes, XC6H4C(CH3)=NOH, were determined by measuring proton-transfer equilibria using an FT-ICR mass spectrometer. The magnitude of the substituent effect on t
