87985-59-9

Basic information

• Product Name: N,Co-(formylmethylene)(octaethylporphyrinato)cobalt(II) chloride
• Synonyms: N,Co-(formylmethylene)(octaethylporphyrinato)cobalt(II) chloride
• CAS NO: 87985-59-9
• Molecular Weight: 669.256
• Mol File: 87985-59-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,Co-(formylmethylene)(octaethylporphyrinato)cobalt(II) chloride(CAS DataBase Reference)
• NIST Chemistry Reference: N,Co-(formylmethylene)(octaethylporphyrinato)cobalt(II) chloride(87985-59-9)
• EPA Substance Registry System: N,Co-(formylmethylene)(octaethylporphyrinato)cobalt(II) chloride(87985-59-9)

Safety Data

• Hazardous Substances Data: 87985-59-9(Hazardous Substances Data)

Upstream product

• 17632-19-8 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine cobalt(II) 
• 6832-13-9 diazoacetaldehyde 

Relevant articles and documents

Reaction of (octaethylporphyrinato)cobalt complexes with diazoacetaldehyde. N-(formylmethyl)- and N-(2-hydroxyethyl)porphyrins

Reaction of divalent and trivalent cobalt complexes of octaethylporphyrin (OEP·H2) with diazoacetaldehyde gave N,Co-(formylmethylene)OEPCoIIIX (X = Cl-, OAc-, ClO4-) which were reduced electrochemically to afford N-(formylmethyl)OEP·H; N-(2,2-dimethoxyethyl)OEP·H and N,N′-(1,2-vinylidene)OEP were obtained from N-(formylmethyl)OEP·H under acidic conditions. NaBH4 reduction of N-(formylmethyl)OEP·H gave N-(2-hydroxyethyl)OEP·H. These N-alkylporphyrins provide a firm basis for the characterization of some suicide metabolites of cytochrome P-450.