879906-26-0Relevant academic research and scientific papers
2-Benzothiazolyl-N-(arenesulfonyl)-sulfinimidoyl fluorides
Pashinnik, Valeriy E.,Guzyr, Alexander I.,Borovikov, Alexei V.,Shermolovich, Yuriy G.
, p. 352 - 356 (2007/10/03)
2-Benzothiazolyl-N-(arenesulfonyl)sulfinimidoyl fluorides were synthesized by the treatment of benzothiazolyl-2-sulfur trifluoride with sulfonamides. The reaction of 2-benzothiazolyl-N(p-toluenesulfonyl)-sulfinimidoyl fluoride with tert-butylamine and morpholine gave 2-benzothiazolyl-N-(arenesulfonyl)- sulfinimidoyl amides. The reaction of 2-benzothiazolyl-N-(p-toluenesulfonyl)- sulfinimidoyl fluoride or 2-benzothiazolyl-15N-(p-tosyl)sulfinimidoyl fluoride with S-trimethylsilylbenzenethiol gave di(benzothiazolyl-2) disulfide, fluorotrimethylsilane and N,N′-bis(p-toluenesulfonyl)-N,N′- bis(phenylthio)-hydrazine or 15N,15N′-bis(p- toluenesulfonyl)-15N, 15N′-bis(phenylthio)- hydrazine, respectively.
