87995-32-2

Basic information

• Product Name: 2-Butenoic acid, 3-phenyl-, phenylmethyl ester
• CAS NO: 87995-32-2
• Molecular Formula: C17H16O2
• Molecular Weight: 252.313
• Mol File: 87995-32-2.mol

Chemical Properties

• CAS DataBase Reference: 2-Butenoic acid, 3-phenyl-, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butenoic acid, 3-phenyl-, phenylmethyl ester(87995-32-2)
• EPA Substance Registry System: 2-Butenoic acid, 3-phenyl-, phenylmethyl ester(87995-32-2)

Safety Data

• Hazardous Substances Data: 87995-32-2(Hazardous Substances Data)

Upstream product

• 187661-86-5 buta-2,3-dienoic acid benzyl ester 
• 98-80-6 phenylboronic acid 

Downstream Products

• 87995-45-7 (E)-4-Benzyloxy-6-phenyl-hepta-1,5-dien-4-ol 
• 87995-39-9 3-Methyl-3-phenyl-hex-5-enoic acid benzyl ester 

Relevant articles and documents

Regio- and Stereoselective Nickel-Catalyzed Coupling of Boronic Acids with Allenoates

The Ni(II)-catalyzed cross-coupling of arylboronic acids with allenoates is documented. The high regio- and stereoselectivity of the process enables a wide range of β-aryl β,γ-unsaturated esters to be prepared in good to excellent yields (up to 95%) and high E / Z -selectivity. Additionally, [3+2]-cascade sequence was observed when 2-formylphenylboronic acid was employed.