87995-33-3Relevant academic research and scientific papers
Ring Construction by Zirconium-promoted Reductive Coupling of Nitriles with Alkenes
Mori, Miwako,Uesaka, Noriaki,Shibasaki, Masakatsu
, p. 1222 - 1224 (2007/10/02)
Intramolecular reductive coupling of nitrile with alkene units in the presence of zirconocene prepared from (C5H5)2ZrCl2 and BuLi gives cyclic ketones; the intermediary metallacycle prepared from the 2-cyano-N-allylaniline derivative is very reactive and
CHEMOSELECTIVITY IN THE CONJUGATE ADDITION OF ALLYLSILANE TO MICHAEL ACCEPTORS
Majetich, George,Casares, Ada M.,Chapman, D.,Behnke, M.
, p. 1909 - 1912 (2007/10/02)
The allylic carbanion species generated by treatment of allylsilane with fluoride ion undergoes highly chemoselective conjugate addition to a series of Michael acceptors for which alternative known allylation procedures proved less general.
