87999-74-4Relevant academic research and scientific papers
Asymmetric pentenylation of aldehydes: A new benchmark for the preparation of ethyl-substituted homoallylic alcohol
Sonawane, Ravindra P.,Joolakanti, Shyamsunder R.,Arseniyadis, Stellios,Cossy, Janine
experimental part, p. 213 - 216 (2009/06/05)
A highly diastereo- and enantioselective boron-mediated pentenylation reaction is presented. The chiral pentenylborane reagents, which are derived from pinene, undergo addition to various aldehydes to afford ethyl-substituted homoallylic alcohols in good
Selective Synthesis of either Branched or Linear Homoallyl Alcohols via the Reaction of Aldehydes with the Allylic Borane-Selenium System
Yamamoto, Yoshinori,Saito, Yoshikazu,Maruyama, Kazuhiro
, p. 5408 - 5409 (2007/10/02)
Either branched (2) or linear (3) homoallyl alcohols can be prepared independently by choosing the reaction conditions through the reaction of (phenylselenyl)allyl carbanion with trialkylboranes.
