88001-79-0

Upstream product

• 83115-12-2 (2,4,6-tri-tert-butylphenyl)phosphine 
• 89218-30-4 tris(tertiobutyl)phenyl-1 dimethylamino-2 phosphapropene-1 
• 89176-09-0 2,4,6-tri-tert-butylphenylphosphine sulfide 
• 10544-50-0 sulfur 
• 114552-12-4 ((CH₃)3C₆H₂)2GeP(C₆H₂(C(CH₃)3)3)S 
• 96481-35-5 dimesitylgerma(2,4,6-tri-tert-butylphenyl)phosphene 
• 159533-00-3 3,3-diphenyl-2-(2,4,6-tri-t-butylphenyl)-1,2-thiaphosphirane 2-sulfide 
• 85421-74-5 (2,4,6-tri-tert-butylphenyl)phosphonothioic dichloride 
• 97067-28-2 C₂₄H₂₀As⁽¹⁺⁾*C₁₈H₂₉ClPS₂^(1-) 
• 89218-29-1 tris(tertiobutyl)phenyl-1 dimethylamino-2 phosphaethylene 
• 83466-54-0 Bis(2,4,6-tri-tert-butylphenyl)diphosphen 
• 87174-74-1 (2,4,6-tri-tert-butylphenyl)bis(trimethylsilyl)phosphine 

Downstream Products

• 1460-02-2 1,3,5-Tri-tert-butylbenzene 
• 89982-42-3 5,7-Di-tert-butyl-3,3-dimethyl-1-thioxo-2,3-dihydro-1H-1λ⁵-phosphindole-1-thiol 
• 97067-26-0 (2,4,6-Tri-tert-butyl-phenyl)-phosphonodithioic acid 
• 83692-00-6 2,4,6-Tris(2,4,6-tri-tert-butylphenyl)-1,3,5-trithia-2,4,6-triphosphorinan 

Relevant academic research and scientific papers

Preparation and X-Ray Structure Analysis of 3,3-Diphenyl-2-(2,4,6-tri-t-butylphenyl)-1,2-thiaphosphirane

Reaction of low coordinated 2,2-diphenyl-1-(2,4,6-tri-t-butylphenyl)phosphaethene with elemental sulfur afforded the corresponding 1,2-thiaphosphirane 2-sulfide 6 via methylene(thioxo)phosphorane 5.Desulfurization reaction of 6 gave the corresponding thia

Transition Metal Substituted Diphosphenes, XIV. On the Reactivity of the Diphosphenyl Complex (η5-C5Me5)(CO)2Fe-P=P-Ar (Ar = 2,4,6-t-Bu3C6H2) towards Sulfur, Selenium, and Tellurium. Synthesis and X-Ray Structure Analysis of the First Thioxo-λ5-diphospenyl Complex (η5-C5Me5)...

The diphosphenyl complex (η5-C5Me5)(CO)2Fe-P=P-Ar (1a) (Ar = 2,4,6-tert-Bu3C6H2) reacts with equimolar amount of sulfur to yield the first thioxo-λ5-diphosphenyl complex (η5-C5Me5)(CO)2Fe-P(=S)=P-Ar (2).Heating of 2 in boiling benzene affords the metal functionalized thiadiphosphirane 3.Similarily the selenoxo-λ5-diphosphenyl complex (η5-C5Me5)(CO)2Fe-P(=S)=P-Ar (5) and selena-diphosphirane 6 are synthesized.The products have been characterized by elemental analysis as well as by spectroscopic data (IR, 1H, 13C, 31P NMR, MS).The molecular structure has been elucidated by single X-ray analysis. - Keywords: Diphosphenyl Complex, Sulfur, Selenium, Tellurium, X-Ray Analysis

From germaphosphene to germathia- (or germaselena-) phosphiranes

Reaction of sulfur (or selenium) with the germaphosphene 1 leads to new stable three-membered heterocycles, the germathiaphosphirane 3 and the germaselenaphosphirane 14. The structure of 3 was confirmed by X-ray crystal analysis (space group P1; a = 11.09

ETUDE DE LA REACTIVITE DU TRIS(TERTIOBUTYL)PHENYLDITHIOPHOSPHORANE

Heating of tris(tertiobutyl)phenyldithiophosphorane gives rise to an isomer with a tetracoordinated phosphorus atom.The action of triphenylphosphine loads to a tricyclophosphathiane which can be transformed in diphosphene by an excess of triphenylphosphine.Reactions with various nucleophilic derivatives (pyridine, triethylamine, diethylamine, butylamine, water, tetraphenylarsonium chloride) are described.

ISOLATION AND CHARACTERIZATION OF A STABLE DITHIOXOPHOSPHORANE

A sterically protected dithioxophosphorane, 2,4,6-tri-t-butylphenyldithioxophosphorane, has been isolated and characterized for the first time as a stable compound.

ETUDE DE L'ACTION DU SOUFRE SUR LA TRIS(TERTIOBUTYL)PHENYLPHOSPHINE

Sterically protected tris(tertiarybutyl)phenylphosphine reacts with sulfur, giving rise to the corresponding sulphide which reacts further to produce bistrithiodiphosphinate.This last compound finally affords the first stable me

SYNTHESIS OF THE FIRST STABLE METADITHIOPHOSPHONATE

Evidence for the formation of the first stable metadithiophosphonate is given.