88008-69-9

Basic information

• Product Name: (C₅H₅)(2-MeC₃H₄)(CO)3(P-i-Pr₃)2MoPt₂
• CAS NO: 88008-69-9
• Molecular Weight: 1010.8
• Mol File: 88008-69-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)(2-MeC₃H₄)(CO)3(P-i-Pr₃)2MoPt₂(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)(2-MeC₃H₄)(CO)3(P-i-Pr₃)2MoPt₂(88008-69-9)
• EPA Substance Registry System: (C₅H₅)(2-MeC₃H₄)(CO)3(P-i-Pr₃)2MoPt₂(88008-69-9)

Safety Data

• Hazardous Substances Data: 88008-69-9(Hazardous Substances Data)

Upstream product

• 12107-35-6 Na[CpMo(CO)3] 
• 88008-70-2 (μ-2-methylallyl)(μ-Br)Pt2(P-i-Pr3)2 

Relevant articles and documents

Stepwise synthesis of heteronuclear Pt2M and PdPtM clusters (M = Cr, Mo, W)

The dinuclear complex (μ-C5H5)(μ-2-MeC3H4)Pt 2(P-i-Pr3)2 (1), which is prepared from (η5-C5H5)Pt-(η3-2-MeC 3H4) and Pt(P-i-Pr3)2, reacts with Me3SiBr to produce the structurally related compound (μ-2-MeC3H4)(μ-Br)Pt2(P-i-Pr 3)2 (4). Reaction of 4 with [(C5H5)M(CO)3]Na (M = Mo, W) leads to displacement of the bridging bromide by the tricarbonyl(cyclopentadienyl)metal anion and formation of the trinuclear clusters (C5H5)(2-MeC3H4)(CO) 3(P-i-Pr3)2Pt2M (5, 6). The analogous mixed-metal PdPtM complexes 9-11 are similarly prepared, starting from (μ-C5H5)(μ-2-MeC3H 4)PdPt(P-i-Pr3)2 (7) via (μ-2-MeC3H4)(μ-Br)-PdPt(P-i-Pr3) 2 (8) as the intermediate that subsequently reacts with [(C5H5)M(CO)3]Na (M = Cr, Mo, W) to form (C5H5)(2-MeC3H4)(CO) 3(P-i-Pr3)2PdPtM (9-11). The IR and 1H, 13C, and 31P NMR spectroscopic data of 5, 6, and 9-11 confirm that the new heteronuclear clusters contain a tetrahedral Pt2MC or PdPtMC framework, the carbon atom of which belongs to a triply bridging CO group.