880090-13-1Relevant articles and documents
A synthetic study of briarane-type marine diterpenoid, pachyclavulide B
Iwasaki, Junya,Ito, Hisanaka,Nakamura, Mitsutake,Iguchi, Kazuo
, p. 1483 - 1486 (2007/10/03)
Enantioselective preparation of the six-membered ring of pachyclavulide B, a briarane-type diterpenoid, was achieved. The key step is desymmetrization of an achiral symmetric substrate by enantiogroup- and diastereoselective epoxidation. The asymmetric ep