880175-94-0

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 862670-48-2 (2R,3R)-1-(tert-Butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-hex-5-en-2-ol 
• 862670-55-1 (R)-4-[(R)-1-(4-methoxybenzyloxy)but-3-enyl]-2,2-dimethyl-1,3-dioxolane 
• 862670-56-2 (2R,3R)-3-(4-Methoxy-benzyloxy)-hex-5-ene-1,2-diol 
• 862670-49-3 (4R,5R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-(4-methoxy-benzyloxy)-tetrahydro-furan-2-ol 
• 108-24-7 acetic anhydride 

Downstream Products

• 862670-61-9 (2R,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-7-(4-methoxy-benzyloxy)-2-methyl-heptanoic acid (2R,3R,5S)-5-[(2R,3R,4R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-4-methyl-tetrahydro-pyran-2-yl]-2-vinyl-tetrahydro-furan-3-yl ester 
• 862670-51-7 Benzoic acid (2R,3R,5S)-5-[(2R,3R,4R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-4-methyl-tetrahydro-pyran-2-yl]-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-yl ester 
• 862670-59-5 Benzoic acid (2R,3R,5S)-5-((2R,3R,4R)-3-benzyloxy-2-methoxy-4-methyl-tetrahydro-pyran-2-yl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-yl ester 
• 862670-60-8 Benzoic acid (2R,3R,5S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-5-((2S,3R,4R)-3-hydroxy-2-methoxy-4-methyl-tetrahydro-pyran-2-yl)-tetrahydro-furan-3-yl ester 
• 679812-26-1 (2R,3R,5S)-5-((2R,3R,4R)-3-Benzyloxy-2-methoxy-4-methyl-tetrahydro-pyran-2-yl)-2-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-3-ol 
• 862670-58-4 Benzoic acid (2R,3R,5S)-5-[(2R,3R,4R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-4-methyl-tetrahydro-pyran-2-yl]-2-hydroxymethyl-tetrahydro-furan-3-yl ester 
• 862670-52-8 Benzoic acid (2R,3R,5S)-5-[(2R,3R,4R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-4-methyl-tetrahydro-pyran-2-yl]-2-vinyl-tetrahydro-furan-3-yl ester 
• 679812-23-8 tert-Butyl-[(2R,3R)-3-(4-methoxy-benzyloxy)-5-phenylsulfanyl-tetrahydro-furan-2-ylmethoxy]-diphenyl-silane 

Relevant academic research and scientific papers

Synthesis of the common left-half part of pectenotoxins

The common left-half [C31-C33(OC1-C7)-C40] part of pectenotoxins has been synthesized convergently from the C31-C35, C36-C40, and C1-C7 parts. The C31-C35 part, prepared via a new route shorter than our previous route, was coupled with the C36-C40 part through reductive lithiation and addition reactions to give an adduct stereoselectively, which was converted to a cyclic acetal corresponding to the C31-C40 part. The left-half was synthesized by a three-step process including esterification of the C31-C40 part with the C1-C7 part.