88044-17-1Relevant academic research and scientific papers
Surface-mediated solid phase reaction. I. Aldol reaction of silyl enol ethers with aldehydes on a solid surface of neutral alumina: Selectivity for anti aldols
Ranu,Chakraborty
, p. 5333 - 5338 (1993)
The aldol reaction of trimethyl silyl enol ethers with aldehydes on the solid surface of neutral alumina under sonication without any solvent is found to proceed providing cross aldol products with anti selectivity.
Uncatalyzed aldol reaction using a dimethylsilyl enolate and α- dimethylsilyl ester in N,N-dimethylformamide
Miura, Katsukiyo,Sato, Hiroshi,Tamaki, Kentaro,Ito, Hajime,Hosomi, Akira
, p. 2585 - 2588 (2007/10/03)
Dimethylsilyl enolates and α-dimethylsilyl esters reacted with aldehydes in N,N-dimethyl-formamide without an activator to give aldol adducts in moderate to good yields. Under the same conditions, the corresponding trimethylsilyl derivatives exhibited lower reactivities toward the aldol reaction.
