88068-45-5Relevant academic research and scientific papers
REACTIONS OF ORGANOLANTHANOID ? COMPLEXES WITH α,β-UNSATURATED CARBONYL COMPOUNDS. SELECTIVE 1,2-ADDITION
Yokoo, Kazuhiro,Yamanaka, Yasuhiro,Fukagawa, Toshihiro,Taniguchi, Hiroshi,Fujiwara, Yuzo
, p. 1301 - 1302 (1983)
Organoytterbium iodide ? complexes (RYbI) react with α,β-unsaturated carbonyl compounds such as acrolein, methyl vinyl ketone, benzalacetone, chalcone, and 2-cyclohexen-1-one to give 1,2-addition products selectively.This high selectivity is explained in terms of the HSAB theory.
