880761-55-7Relevant articles and documents
A direct organocatalytic entry to sphingoids: Asymmetric synthesis of D-arabino- and L-ribo-phytosphingosine
Enders, Dieter,Palecek, Jiri,Grondal, Christoph
, p. 655 - 657 (2006)
The organocatalytic asymmetric synthesis of d-arabino- and l-ribo-phytosphingosine is described employing a diastereo- and enantioselective (S)-proline-catalyzed aldol reaction of 2,2-dimethyl-1,3-dioxan-5-one and pentadecanal as the key step. The Royal S