88078-73-3Relevant academic research and scientific papers
Rate constants for reaction of a fluorous tin hydride reagent with primary alkyl radicals
Horner, John H.,Martinez, Felix N.,Newcomb, Martin,Hadida, Sabine,Curran, Dennis P.
, p. 2783 - 2786 (2007/10/03)
Rate constants for 6-exo cyclization of the 7,7-diphenyl-6-heptenyl radical (3) in benzotrifluoride (BTF, PhCF3) were determined by laser flash photolysis, and radical clock 3 was used in competition kinetic studies for determination of rate co
Polar substituent and solvent effects on the kinetics of radical reactions with thiols
Tronche, Christopher,Martinez, Felix N.,Horner, John H.,Newcomb, Martin,Senn, Martin,Giese, Bernd
, p. 5845 - 5848 (2007/10/03)
The rates of thiol trapping of radicals depend upon polar substituents and solvent effects. The rate accelerating effect of water on the reactions of biologically relevant radicals is of special importance.
