88083-18-5

Basic information

• Product Name: 2-Propenoic acid, 3-[(3-phenyl-2-propenyl)oxy]-, (E,E)-
• CAS NO: 88083-18-5
• Molecular Formula: C12H12O3
• Molecular Weight: 204.225
• Mol File: 88083-18-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-[(3-phenyl-2-propenyl)oxy]-, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-[(3-phenyl-2-propenyl)oxy]-, (E,E)-(88083-18-5)
• EPA Substance Registry System: 2-Propenoic acid, 3-[(3-phenyl-2-propenyl)oxy]-, (E,E)-(88083-18-5)

Safety Data

• Hazardous Substances Data: 88083-18-5(Hazardous Substances Data)

Upstream product

• 54299-83-1 (E)-(2-carboxyvinyl)trimethylammonium betaine 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 

Downstream Products

• 147460-94-4 (2E)-methyl 3-(cinnamyloxy)acrylate 
• 939-21-9 3-phenyl-4-pentenal 
• 868705-49-1 ((2E)-3-(cinnamyloxy)allyloxy)triisopropylsilane 
• 868705-47-9 (2E)-3-(cinnamyloxy)prop-2-en-1-ol 

Relevant articles and documents

Stereoselective Synthesis of β-Alkoxy- and β-Alkylthio-Acrylic Esters and Amides from β-Tosylacrylic Derivatives

A simple and stereoselective synthesis of β-alkoxy- and β-alkylthio-acrylic esters and amides (8) by nucleophilic vinylic substitution of the tosyl group by sodium alcoholates and thiolates of (E)-β-tosylacrylic derivatives (7), prepared by iodosulfonylation-dehydroiodination of acrylic compounds, is described.This methodology is applied to the synthesis of sinharine (8eh) a natural antifungal isolated from glycosmis cyanocarpa.

Preparation and Rearrangement of trans-3-(Allyloxy)acrylic Acids: A Claisen Sequence That Avoids Mercury Catalysis

Reaction of sodium or lithium salts of primary and secondary allylic alcohols with (E)-(carboxyvinyl)trimethylammonium betaine affords (E)-3-(allyloxy)acrylic acids, which on heating are transformed to γ,δ-unsaturated aldehydes.