88095-36-7

Basic information

• Product Name: (4aR,8R,8aS)-8-(2-Methyl-allyl)-2-phenyl-4,4a,8,8a-tetrahydro-pyrano[3,2-d][1,3]dioxine
• CAS NO: 88095-36-7
• Molecular Weight: 272.344
• Mol File: 88095-36-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4aR,8R,8aS)-8-(2-Methyl-allyl)-2-phenyl-4,4a,8,8a-tetrahydro-pyrano[3,2-d][1,3]dioxine(CAS DataBase Reference)
• NIST Chemistry Reference: (4aR,8R,8aS)-8-(2-Methyl-allyl)-2-phenyl-4,4a,8,8a-tetrahydro-pyrano[3,2-d][1,3]dioxine(88095-36-7)
• EPA Substance Registry System: (4aR,8R,8aS)-8-(2-Methyl-allyl)-2-phenyl-4,4a,8,8a-tetrahydro-pyrano[3,2-d][1,3]dioxine(88095-36-7)

Safety Data

• Hazardous Substances Data: 88095-36-7(Hazardous Substances Data)

Upstream product

• 5987-33-7 4,6-O-benzylidene-D-allal 
• 5674-01-1 2-methylallylmagnesium chloride 
• 88095-31-2 1,5-anhydro-4,6-O-benzylidene-2-deoxy-3-O-mesyl-D-ribo-hex-1-enitol 

Relevant articles and documents

REACTION OF 4,6-O-BENZYLIDENE-3-O-MESYL-ALLAL WITH ALLYLIC GRIGNARD REAGENTS. HIGHLY REGIO- AND STEREOSELECTIVE PREPARATION OF 2,6-DISUBSTITUTED DIHYDROPYRAN RINGS

The reaction of 4,6-O-benzylidene-1,2-dideoxy-3-O-mesyl-D-ribo-hex-1-enopyranose reacted with 2-propenylmagnesium chloride or 2-methyl-2-propenylmagnesium chloride to give 1,5-anhydro-4,6-O-benzylidene-2,3-dideoxy-1-C-prop-2-enyl- (or 2-methylprop-2-enyl)-β-D-erythro-hex-2-enitol in good yield.