88111-91-5

Basic information

• Product Name: 1H-Cyclopentcisoxazole-3,4,5,6-tetrol, hexahydro-1-methyl-, 3S-(3.alpha.,3a.beta.,4.beta.,5.alpha.,6.beta.,6a.beta.)-
• Synonyms: 1H-Cyclopentcisoxazole-3,4,5,6-tetrol, hexahydro-1-methyl-, 3S-(3.alpha.,3a.beta.,4.beta.,5.alpha.,6.beta.,6a.beta.)-
• CAS NO: 88111-91-5
• Molecular Formula: C7H13NO5
• Molecular Weight: 191.18
• Mol File: 88111-91-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1H-Cyclopentcisoxazole-3,4,5,6-tetrol, hexahydro-1-methyl-, 3S-(3.alpha.,3a.beta.,4.beta.,5.alpha.,6.beta.,6a.beta.)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Cyclopentcisoxazole-3,4,5,6-tetrol, hexahydro-1-methyl-, 3S-(3.alpha.,3a.beta.,4.beta.,5.alpha.,6.beta.,6a.beta.)-(88111-91-5)
• EPA Substance Registry System: 1H-Cyclopentcisoxazole-3,4,5,6-tetrol, hexahydro-1-methyl-, 3S-(3.alpha.,3a.beta.,4.beta.,5.alpha.,6.beta.,6a.beta.)-(88111-91-5)

Safety Data

• Hazardous Substances Data: 88111-91-5(Hazardous Substances Data)

Upstream product

• 88111-83-5 (1R,5S)-6-exo,7-endo,8-exo-triacetoxy-N-methyl-4-endo-phenylthio-3-oxa-2-azabicyclo<3.3.0>octane 
• 88111-90-4 (3S,3aS,4R,5S,6S,6aR)-1-Methyl-3-phenylsulfanyl-hexahydro-cyclopenta[c]isoxazole-4,5,6-triol 
• 88111-90-4 (1R,5S)-6-exo,7-endo,8-exo-trihydroxy-N-methyl-4-endo-phenylthio-3-oxa-2-azabicyclo<3.3.0>octane 

Downstream Products

• 88111-89-1 (1R,5S)-4-exo,6-exo,7-endo,8-exo-tetra-acetoxy-N-methyl-3-oxa-2-azabicyclo<3.3.0>octane 

Relevant articles and documents

Functionalised Carbocycles from Carbohydrates. Part 2. The Synthesis of 3-Oxa-2-azabicyclooctanes. X-Ray Crystal Structure of (1R,5S)-6-exo,7-endo,8-exo-Triacetoxy-N-methyl-4-endo-phenylthio-3-oxa-2-azabicyclooctane

Treatment of various 6-bromo-6-deoxy- and 6-deoxy-6-iodo-D-glucopyranosyl compounds with zinc in ethanol affords acyclic 5,6-dideoxy-D-xylo-hex-5-enoses which have been converted into 3-oxa-2-azabicyclooctanes containing functional groups which per